I think you may be approaching this from the wrong end, assuming you're talking about the Library created within XBMC/SPMC/Kodi. The Library will be empty until you point it to specific folder(s) and mark them as TV series/Film/generic.
If you're using the Confluence pack from our Wizard, you can click on the Videos menu from XBMC's homescreen, then select files. If you have problems following the onscreen steps from this point, let us know. If you're currently using the Modded pack from the DroidBOX Wizard, please let me know and I'll write up the relevant steps for you.